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Invention Cleans Oil, Decontaminates Water;
“New Catalyst” Likely To Revolutionize
An artistic rendering of a nanogrid.
Photocatalytic nanogrids™ utilize the whole solar spectrum, can work in
water for a long time and can be used over and over again.
Oil spills do untold damage to the environment, to the waters they pollute
and to marine and other wildlife. The Deepwater Horizon spill in the Gulf of
Mexico in 2010, for example, the largest accidental marine oil spill in the
history of the petroleum industry, flowed unabated for three months.
Typically, such oil spills are extraordinarily difficult to clean up. Soon,
however, the process may become infinitely easier and ecologically friendly,
the result of a new invention by a National Science Foundation (NSF)
Pelagia-Irene (Perena) Gouma, a professor in the Department of Materials
Science and Engineering at the State University of New York (SUNY) Stony
Brook, created a novel ‘nanogrid’, a large net consisting of metal grids
made of a copper tungsten oxide, that, when activated by sunlight, can break
down oil from a spill, leaving only biodegradable compounds behind.
“We have made a new catalyst that can break down hydrocarbons in water, and
it does not contaminate the water,” says Gouma, who also directs SUNY’s
Center for Nanomaterials and Sensor Development. “It utilizes the whole
solar spectrum and can work in water for a long time, which no existing
photocatalyst can do now. Ours is a unique technology. When you shine light
on these grids, they begin to work and can be used over and over again.
“Something like this would work fine for any oil spill,” Gouma adds. “Any
ship can carry them, so if they have even a small amount of spill, they can
take care of it.”
Initially, the grids, which resemble non-woven mats of miniaturized ceramic
fishing nets, probably will be used for oil spills, although they
potentially could prove valuable in other applications, such as cleaning
contaminated water produced by ‘fracking’, the process of hydraulic
fracturing to extract natural gas from shale, and as well as from other
“Fracking is a reality,” she says. “It is happening. If the science and
engineering we produce in the lab can help alleviate environmental problems,
we will be happy about that.”
Because they work well both in water and air, they also could be a
chemical-free, possibly even water-free, method of cleaning clothes in the
future. “The dry cleaning process that we now use involves a lot of
contaminants that have to be remediated and treated, such as benzene,” she
says. “This could be a dry cleaning substitute that would be more
environmentally friendly than current dry cleaning approaches.”
Moreover, “imagine you lay this over your clothes, and expose them to light.
You won’t need a washing machine, or chemicals, or even water,” she adds.
The photocatalytic nanogrids™ invented in her lab are made by a unique
self-assembly process that occurs “during the nanomanufacturing on non-woven
nanofibrous mats deposited on metal meshes,” according to Gouma. “Upon
heating, metal clusters diffuse inside polymeric nanofibers, then turn into
single crystal nanowires, then oxidize to form metal oxide -ceramic-
nanoparticles, that are interconnected, like links in a chain,” she says.
These form an unusual and “robust third architecture that allows for the
highest surface area, providing maximum exposure to the contaminant to be
remediated, while the nanoscale particle sizes enable fast catalytic
action,” she adds. “The result is a self-supported water remediation
targeted photocatalytic technology that has no precedent.”
In the fall of 2011, Gouma was the first scientist to receive a $50,000 NSF
Innovation Corps (I-Corps) award, which supports a set of activities and
programs that prepare scientists and engineers to extend their focus beyond
the laboratory into the commercial world.
Such results may be translated through I-Corps into technologies with
near-term benefits for the economy and society. It is a public-private
partnership program that teaches grantees to identify valuable product
opportunities that can emerge from academic research, and offers
entrepreneurship training to faculty and student participants.
“The I-Corps program was very useful for the students,” she says. “It got
them involved, and got them to realize that there is a practical application
to what they do. It was extremely useful for them to see how something
developed in the lab could be used in the field, and that you actually can
start a business from something started in the lab.”
She and her team are in the process of creating a startup business, they
have two patents pending on the process, with the hope of scaling up
production and carrying out pilot studies.
“We want to demonstrate feasibility in the real world, and then produce them
in large quantities,” she says. “We have proof of principle that our
technology can be useful. Our technique works in the lab. We now need to
make sure that it works in the field.”
- Marlene Cimons, National Science Foundation (source: www.nsf.gov/discoveries)
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